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Theories of Hydrophobic Effects and the Description of Free Volume in Complex Liquids

arXiv:physics/9806036

Abstract

Recent progress on molecular theories of hydration of nonpolar solutes in aqueous solution has led to new ways of thinking about the old issue of free, or "available," volume in liquids. This article surveys the principal new results with particular attention to general issues of packing in liquids.

14 pages included 3 figures; submitted to the proceedings of the NATO Advanced Study Institute: New Approaches to Old and New Problems in Liquid State Theory, Patti Marina (Messina) Italy, July 1998 replacement: minor typographical corrections