Optical Manipulation of Long-range Interactions at the 3s+3p Asymptote of Na$_2$

Abstract

We investigate the influence of a laser field, which is near-resonant to the atomic sodium 3$^2$P$_{1/2}$ $\to$ 3$^2$D$_{3/2}$ transition, on the last bound levels of the A$^1Σ^+_u$ state in Na$_2$. In a molecular beam experiment level shifts up to $\approx$ 100 MHz and light induced line broadenings were observed using an optical double resonance excitation scheme. Moreover, the coupling laser can reduce the number of bound levels of the A state by one or more units, which effectively means that in the picture of a collision of a 3$^2$S$_{1/2}$ and a 3$^2$P$_{1/2}$-atom the scattering phase is altered by more than $π$. The observed effects are interpreted as light induced couplings of the A$^1Σ^+_u$ state, which correlates to the 3s$_{1/2}$+3p$_{1/2}$ asymptote, to the $4^1Σ^+_g$ and $2^1Π_g$ states at the 3s$_{1/2}$+3d$_{3/2}$ asymptote. We performed multi-channel calculations, applying the mapped Fourier grid method, which reproduce our experimentally observed level shifts well.

12 pages; PACS: 34.50.Rk: Laser-modified scattering and reactions; 33.80.-b: Photon interactions with molecules; 42.62.Fi: Laser spectroscopy