Strong-coupling expansions for the anharmonic Holstein model and for the Holstein-Hubbard model

Abstract

A strong-coupling expansion is applied to the anharmonic Holstein model and to the Holstein-Hubbard model through fourth order in the hopping matrix element. Mean-field theory is then employed to determine transition temperatures of the effective (pseudospin) Hamiltonian. We find that anharmonic effects are not easily mimicked by an on-site Coulomb repulsion, and that anharmonicity strongly favors superconductivity relative to charge-density-wave order. Surprisingly, the phase diagram is strongly modified by relatively small values of the anharmonicity.

34 pages, typeset in ReVTeX, 11 encapsulated postscript files included