Large Ca Isotope Effect in CaC6

Abstract

We have measured the Ca isotope effect in the newly discovered superconductor CaC6. The isotope effect coefficient is 0.50(7). If one assumes that this material is a conventional electron-phonon coupled superconductor, this result shows that the superconductivity is dominated by coupling of the electrons by Ca phonon modes and that C phonons contribute very little. Thus, in contrast to MgB2, where phonons in the B layers are responsible for the superconductivity, in CaC6 the phonons are primarily modes of the intercalated Ca.

11 pages including 2 Figures