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Nonequivalent ensembles and metastability

arXiv:cond-mat/0501390 · doi:10.1142/9789812701558_0009

Abstract

This paper reviews a number of fundamental connections that exist between nonequivalent microcanonical and canonical ensembles, the appearance of first-order phase transitions in the canonical ensemble, and thermodynamic metastable behavior.

4 pages, RevTeX, 1 figure. Contribution to the Proceedings of the 31st Workshop of the International School of Solid State Physics ``Complexity, Metastability and Nonextensivity'', held at the Ettore Majorana Foundation and Centre for Scientific Culture, Erice, Sicily, Italy, July 2004. Edited by C. Tsallis, A. Rapisarda and C. Beck. To be published by World Scientific, 2005