Field-induced structural evolution in the spin-Peierls compound CuGeO$_3$: high-field ESR study

Abstract

The dimerized-incommensurate phase transition in the spin-Peierls compound CuGeO$_3$ is probed using multifrequency high-resolution electron spin resonance (ESR) technique, in magnetic fields up to 17 T. A field-induced development of the soliton-like incommensurate superstructure is clearly indicated as a pronounced increase of the ESR linewidth $ΔB$ (magnon excitations), with a $ΔB_{max}$ at $B_{c}\sim$ 13.8 T. The anomaly is explained in terms of the magnon-soliton scattering, and suggests that the soliton-like phase exists close to the boundary of the dimerized-incommensurate phase transition. In addition, magnetic excitation spectra in 0.8% Si-doped CuGeO$_3$ are studied. Suppression of the $ΔB$ anomaly observed in the doped samples suggests a collapse of the long-range-ordered soliton states upon doping, that is consistent with high-field neutron scattering experiments.

Accepted to Phys. Rev. B