Spin-Wave Description of Nuclear Spin-Lattice Relaxation in Mn_{12}O_{12} Acetate

Abstract

In response to recent nuclear-magnetic-resonance (NMR) measurements on the molecular cluster Mn_{12}O_{12} acetate, we study the nuclear spin-lattice relaxation rate 1/T_1 developing a modified spin-wave theory. Our microscopic new approach, which is distinct from previous macroscopic treatments of the cluster as a rigid spin of S=10, not only excellently interprets the observed temperature and applied-field dependences of 1/T_1 for ^{55}Mn nuclei but also strongly supports the ^{13}C NMR evidence for spin delocalization over the entire molecule.

to be published in Phys. Rev. Lett., 4 pages, 4 figures embedded