Field dependent anisotropy change in a supramolecular Mn(II)-[3x3] grid
arXiv:cond-mat/0201090 · doi:10.1103/PhysRevLett.88.066401
Abstract
The magnetic anisotropy of a novel Mn(II)-[3x3] grid complex was investigated by means of high-field torque magnetometry. Torque vs. field curves at low temperatures demonstrate a ground state with S > 0 and exhibit a torque step due to a field induced level-crossing at B* \approx 7.5 T, accompanied by an abrupt change of magnetic anisotropy from easy-axis to hard-axis type. These observations are discussed in terms of a spin Hamiltonian formalism.
4 pages, 4 figures, to be published in Phys. Rev. Lett