Collisional Excitation and Weak Maser Action of Interstellar Methanimine
arXiv:1806.01517 · doi:10.1021/acs.jpclett.8b01431
Abstract
The inelastic cross sections and rate coefficients for the rotational excitation of methanimine (CH$_2$NH) by cold H$_2$ have been determined quantum mechanically based on a new highly correlated five-dimensional potential energy surface. This surface was fitted to more than 60 000 ab initio points with a root mean square error of $\sim$ 1-2 cm$^{-1}$ in the region of the potential well whose depth is -374.0 cm$^{-1}$. The rotationally inelastic rate coefficients have been combined with spectroscopic data to generate the non-equilibrium spectrum of CH$_2$NH towards the interstellar molecular cloud Sgr~B2(N). The transition $1_{10}\to 1_{11}$ at 5.29 GHz is found to be inverted and the predicted weak maser emission spectrum is in excellent agreement with new observations performed with the 100-meter Green Bank Telescope.
16 pages, 4 figures