Probing quantum coherence in ultrafast molecular processes: an ab initio approach to open quantum systems

Abstract

Revealing possible long-living coherence in ultrafast processes allows detecting genuine quantum mechanical effects in molecules. To investigate such effects from a quantum chemistry perspective, we have developed a method for simulating the time evolution of molecular systems, based on ab initio calculations that includes relaxation and environment-induced dephasing of the molecular wave function, whose rates are external parameters. The proposed approach combines a quantum chemistry description of the molecular target with a real-time propagation scheme within the time-dependent stochastic Schroedinger equation. Moreover, it allows a quantitative characterization of the state and dynamics coherence, through the l1-norm of coherence and the linear entropy, respectively. To test the approach, we have simulated femtosecond pulse-shaping ultrafast spectroscopy of terrylenediimide, a well studied fluorophore in single-molecule spectroscopy. Our approach is able to reproduce the experimental findings [R. Hildner et al.,Nature Phys., 7, 172 (2011)], confirming the usefulness of the approach and the correctness of the implementation.

This is the final version accepted for publication of a work that is appearing in Journal of Chemical Physics (Copyright AIP)