Negative Entropies in Casimir and Casimir-Polder Interactions

Abstract

It has been increasingly becoming clear that Casimir and Casimir-Polder entropies may be negative in certain regions of temperature and separation. In fact, the occurrence of negative entropy seems to be a nearly ubiquitous phenomenon. This is most highlighted in the quantum vacuum interaction of a nanoparticle with a conducting plate or between two nanoparticles. It has been argued that this phenomenon does not violate physical intuition, since the total entropy, including the self-entropies of the plate and the nanoparticle, should be positive. New calculations, in fact, seem to bear this out at least in certain cases.

8 pages, 12 figures, extended version of talk at Frontiers of Quantum and Mesoscopic Thermodynamics, Prague, 2015