Interfacial colloidal monolayers under steady shear: structure and flow profiles

Abstract

We study the coupling between the structural dynamics and rheological response of charged colloidal monolayers at water/oil interfaces, driven into steady shear by a microdisk rotating at a controlled angular velocity. The flow causes particles to layer into rotating concentric rings linked to the local, position-dependent shear rate, which triggers two distinct dynamical regimes: particles move continuously "Flowing") close to the microdisk, or exhibit intermittent "Hopping" between local energy minima farther away. The shear-rate dependent surface viscosity of a monolayer can be extracted from an interfacial stress balance, giving "macroscopic" flow curves whose behavior corresponds to the distinct microscopic regimes of particle motion. Hopping Regions correspond to a surface yield stress $η\sim τ_S^Y \dotγ^{-1}$, whereas Flowing Regions exhibit surface viscosities with power-law shear-thinning characteristics.

Supplementary Materials also present. Soft Matter, 2015