Imaging spectroscopy of rubidium atoms attached to helium nanodroplets

Abstract

Highly excited states of rubidium (Rb) atoms attached to helium (He) nanodroplets are studied by two-photon ionization spectroscopy in combination with electron and ion imaging. Photoion spectra and angular distributions are in good agreement with a pseudodiatomic model for the RbHe_N complex. Repulsive interactions in the excited states entail fast dissociation followed by ionization of free Rb atoms as well as of RbHe and RbHe_2 exciplexes. Nonresonant excitation generates Rb atoms in low-lying electronic levels by statistical evaporation-like desorption.